Reaction of 1-methyl-1-cyclopentadienyl-1-silacyclobutane with Fe2(CO)9

  • A. L. Bykova
  • O. V. Kuz'min
  • I. B. Gryaznova
  • A. Ya. Sideridu
  • A. V. Lebedev
Brief Communications
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Conclusions

  1. 1.

    Complexation with the participation of the cyclopentadienyl ring in 1-methyl-1-cyclopentadienyl-1-silacyclobutane proceeds more readily than cleavage of the endocyclic Si-C bond of the silacyclobutane ring.

     
  2. 2.

    Complex (III) has catalytic activity in the conversion of thiols to disulfides.

     

Keywords

Catalytic Activity Disulfide Thiol Silacyclobutane 

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Literature cited

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    C. S. Kraihanzel and J. Conville, J. Organomet. Chem.,23, 357 (1970).Google Scholar
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    E. W. Abel and S. Moorhause, J. Organomet. Chem.,28, 211 (1971).Google Scholar
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    C. S. Cundy and M. F. Lappert, J. Chem. Soc., Chem. Commun., 445 (1972).Google Scholar
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    K. H. Pannel, A. R. Bassindale, and J. W. Fitch, J. Organomet. Chem.,209, C65 (1981).Google Scholar
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    L. Parkanyi, K. H. Pannel, and C. Herbanzel, J. Organomet. Chem.,252, 127 (1983).Google Scholar

Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • A. L. Bykova
    • 1
    • 2
  • O. V. Kuz'min
    • 1
    • 2
  • I. B. Gryaznova
    • 1
    • 2
  • A. Ya. Sideridu
    • 1
    • 2
  • A. V. Lebedev
    • 1
    • 2
  1. 1.A. V. Topchiev Institute of Petrochemical SynthesisAcademy of Sciences of the USSRMoscow
  2. 2.State Research Institute for the Chemistry and Technology of Heteroorganic CompoundsMoscow

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