Reaction of arylarsonic acids with organylalkoxy- and organylacetoxy-silanes

  • M. G. Voronkov
  • S. V. Basenko
  • I. A. Gebel'
  • R. G. Mirskov
Brief Communications
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Conclusions

The reaction of phenylarsonic acid with trialkylalkoxy- or trialkylacetoxysilanes leads to the formation of bis(trialkylsilyl)phenylarsonates. Bis(trimethylsilyl)- and bis(dimethylsilyDphenylarsonates are thermally unstable and decompose upon separation.

2. The reaction of phenylarsonic acid with organylalkoxy- or tetraalkoxysilanes is a convenient method for the preparation of dialkylphenylarsonates.

Keywords

Trimethylsilyl Convenient Method Phenylarsonic Acid Phenylarsonates 

Literature cited

  1. 1.
    R. M. Kary and K. C. Frisch, J. Am. Chem. Soc.,79, 2140 (1957).Google Scholar
  2. 2.
    US Patent No. 2,863,893; Chem. Abstr.,53, 9148 (1959).Google Scholar
  3. 3.
    USSR Inventor's Certificate No. 170,968; Byull. Izobret., No. 10, 28 (1965).Google Scholar
  4. 4.
    USSR Inventor's Certificate No. 1,268,591; Byull. Izobret., No. 41, 91 (1986).Google Scholar
  5. 5.
    A. J. Dale and P. Froyen, Acta Chem. Scand.,31, 599 (1977).Google Scholar
  6. 6.
    V. S. Gamayurova, M. G. Kralichkina, and B. D. Chernokal'skii, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol.,15, 1023 (1972).Google Scholar

Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • M. G. Voronkov
    • 1
  • S. V. Basenko
    • 1
  • I. A. Gebel'
    • 1
  • R. G. Mirskov
    • 1
  1. 1.Irkutsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRUSSR

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