Dimerization of vinylcyclopropane and its codimerization with 1,3-dienes catalyzed by cobalt complexes

  • U. M. Dzhemilev
  • R. I. Khusnutdinov
  • N. A. Shchadneva
Organic Chemistry


The dimerization of vinylcyclopropane to 2-cyclopropyl-1,5(Z)-heptadiene and the codimerization of vinylcyclopropane with 1,3-dienes (butadiene, isoprene, and 2-cyclopropylbutadiene) with the formation of 2-cyclopropyl-1,4-hexadienes were carried out in the presence of the catalytic systems Co(acac)3-1,2-bis(diphenylphosphino)ethane [1,2-bis(diphenylphosphino)methane]-AlEt2Cl.


Methane Cobalt Ethane Acac Catalytic System 
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Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • U. M. Dzhemilev
    • 1
  • R. I. Khusnutdinov
    • 1
  • N. A. Shchadneva
    • 1
  1. 1.Institute of Chemistry, Bashkir Scientific Center, Urals BranchAcademy of Sciences of the-USSRUfa

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