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Direct13C-13C spin-spin coupling constants for the triple bond in activated acetylenes

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

13C-13C SSCC values across the triple bond in activated acetylenes are determined primarily by the σ-electronic properties of substituents. The enhanced sensitivity of1Jcc in acetylene derivatives to substituent effects also asserts their possible utility in estimating the electronegative properties of substituents.

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Authors and Affiliations

  1. A. A. Zhdanov Irkutsk State University, USSR

    L. B. Krivdin, V. V. Shcherbakov, A. I. Gritsa, A. G. Mal'kina & Yu. M. Skvortsov

  2. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    L. B. Krivdin, V. V. Shcherbakov, A. I. Gritsa, A. G. Mal'kina & Yu. M. Skvortsov

Authors
  1. L. B. Krivdin
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  2. V. V. Shcherbakov
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  3. A. I. Gritsa
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  4. A. G. Mal'kina
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  5. Yu. M. Skvortsov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1287–1292, June, 1988.

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Krivdin, L.B., Shcherbakov, V.V., Gritsa, A.I. et al. Direct13C-13C spin-spin coupling constants for the triple bond in activated acetylenes. Russ Chem Bull 37, 1132–1136 (1988). https://doi.org/10.1007/BF00961916

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  • DOI: https://doi.org/10.1007/BF00961916

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