The effect of a liquid crystal medium on the decomposition ofρ-nitrophenyl dimethylthiophosphate

  • R. F. Bakeeva
  • V. E. Bel'skii
  • L. A. Kudryavtseva
  • G. V. Dmitrieva
  • B. E. Ivanov
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Abstract

The lamellar liquid crystal meso phase formed in the cetyltrimethylammonium bromide-1-hexanol-water system assists the reaction of p-nitrophenyl dimethyl thiophosphate with a charged nucleophile (hexanolate anion) and uncharged nucleophile (ethylenediamine) with the loss of the p-nitrophenylmethylthiophosphate anion, i.e., the reaction at the carbon atom and not at the phosphorus atom.

Keywords

Phosphorus Carbon Atom Dimethyl Liquid Crystal Meso 

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Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • R. F. Bakeeva
    • 1
  • V. E. Bel'skii
    • 1
  • L. A. Kudryavtseva
    • 1
  • G. V. Dmitrieva
    • 1
  • B. E. Ivanov
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan BranchAcademy of Sciences of the USSRUSSR

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