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Acid chlorides of O-alkylchloroformimino-O-alkylphosphoric acids

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Reaction of 1,1-dichloro-1-nitrosoalkanes with dialkyl chlorophosphites yields acid chlorides of O-alkylchloroformimino-O-alkylphosphoric acids. Hydrolysis of these compounds leads to nucleophilic substitution of the Cl atom at the phosphorus atom and not that in the alkylchloroformimino part of the molecule. The O-alkylchloroformimino-O-alkylphosphoric acids were isolated and characterized in the form of the corresponding ammonium salts.

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Literature cited

  1. I. V. Martynov, A. N. Ivanov, T. A. Epishina, and V. B. Sokolov, Izv. Akad. Nauk SSSR, Ser. Khim., No. 5, 1086 (1987).

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  2. V. B. Sokolov, A. N. Ivanov, T. A. Epishina, and I. V. Martynov, Zh. Obshch. Khim.,57, No. 7, 1659 (1987).

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  3. I. V. Martynov, A. N. Ivanov, T. A. Epishina, and V. B. Sokolov, Izv. Akad. Nauk SSSR, Ser. Khim., No. 12, 2854 (1987).

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Authors and Affiliations

  1. Institute of Physiologically Active Compounds, Academy of Sciences of the USSR, Chernogolovka

    V. B. Sokolov, A. N. Ivanov, T. V. Goreva, T. A. Epishina & I. V. Martynov

Authors
  1. V. B. Sokolov
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  2. A. N. Ivanov
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  3. T. V. Goreva
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  4. T. A. Epishina
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  5. I. V. Martynov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1122–1125, May, 1990.

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Sokolov, V.B., Ivanov, A.N., Goreva, T.V. et al. Acid chlorides of O-alkylchloroformimino-O-alkylphosphoric acids. Russ Chem Bull 39, 1007–1010 (1990). https://doi.org/10.1007/BF00961702

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  • DOI: https://doi.org/10.1007/BF00961702

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