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Redox reactions of 3,6-di-tert-butyl-ortho-benzoquinone, catalyzed by tetrafluorosilane

  • A. K. Chekalov
  • N. G. Gvazava
  • V. B. Vol'eva
  • T. I. Prokof'eva
  • A. I. Prokof'ev
  • V. V. Ershov
Organic Chemistry
  • 41 Downloads

Abstract

Tetrafluorosilane- catalyzed redox reactions of 3,6-di-tert-butyl-ortho-benzoquinone have been examined. From the EPR spectroscopic data and a study of the reaction products, a mechanism for these reactions is proposed involving the formation of a quinone- tetrafluorosilane complex which has strong oxidizing properties, and which enables the original quinone to undergo further reactions.

Keywords

Quinone Redox Reaction Spectroscopic Data Catalyze Redox Reaction Tetrafluorosilane 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • A. K. Chekalov
    • 1
  • N. G. Gvazava
    • 1
  • V. B. Vol'eva
    • 1
  • T. I. Prokof'eva
    • 1
  • A. I. Prokof'ev
    • 1
  • V. V. Ershov
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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