Reaction of trichloroacetyl isocyanate with some β-diketones

  • B. A. Arbuzov
  • N. N. Zobova
  • S. K. Yakupova
Organic Chemistry


Benzoylacetone and 2-acetyl-1-cyclopentanone react in the enolic forms with trichloroacetyl isocyanate to give the corresponding O-addition products, which then rearrange to the C-addition products.


Isocyanate Enolic Form Benzoylacetone Trichloroacetyl Trichloroacetyl Isocyanate 
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Literature cited

  1. 1.
    B. A. Arbuzov, N. N. Zobova, and O. V. Sofronova, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 1910.Google Scholar
  2. 2.
    J. W. Emsley, et al., High Resolution Nuclear Magnetic Resonance Spectroscopy, Vol. 1, Pergamon (1966).Google Scholar
  3. 3.
    F. B. Balabanova, Dissertation, Kazan (1973).Google Scholar
  4. 4.
    A. I. Kol'tsov, Yu. A. Ignat'ev, V. V. Kopeikin, and E. F. Panarin, Zh. Org. Khim.,12, 2036 (1976).Google Scholar
  5. 5.
    L. J. Bellamy, Infrared Spectra of Complex Molecules, Wiley (1958).Google Scholar
  6. 6.
    O. V. Sofronova, Dissertation, Kazan (1977).Google Scholar
  7. 7.
    J. Heilbron and H. M. Banbury, Dictionary of Organic Compounds [Russian translation], Vol. 1, IL (1949), p. 15.Google Scholar
  8. 8.
    Chemistry Handbook [in Russian], Vol. 2, Khimiya (1971), p. 452.Google Scholar

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • B. A. Arbuzov
    • 1
  • N. N. Zobova
    • 1
  • S. K. Yakupova
    • 1
  1. 1.V. I. Ul'yanov-Lenin Kazan State UniversityUSSR

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