Conclusions
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1.
The oxidative hydroboration of 3-methylbicyclo[4.1.0]-2-heptene proceeds stereoseleetively to give cls-3-methylbicyclo[4.1.0]heptan-trans-2-ol.
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2.
The hydrogenolysis of cis-3-methylbicyclo[4.1.0]-2-heptanone gives cis-3-methylbicyclo[4.1.0]heptantrans-2-ol; the hydrogenolysis of trans-3-methylbicyclo[4.1.0]-2-heptanone leads to the formation of the alcohols trans-3-mettoylbicyclo[4.1.0]heptan-cis-2-ol and trans-3-methylbicyclo[4.1.0]heptan-trans-2-ol in a. 1.2∶1 ratio.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 875–878, April 1980.