Skip to main content
SpringerLink
Log in

GLC study of some physicochemical properties of dibenzenechromium and its alkyl derivatives

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Enthalpy, free energy, and entropy of the solution of methyl- and ethyl-substituted dibenzenechromium complexes, and also bridged 1.1'-tetramethylenedibenzenechromium in a siloxane elastomer SKTFV-803 were determined by means of GLC. The reaction of bisarenechromium complexes with the liquid phase of SKTFV-803 was shown.

  2. 2.

    The coefficients of the equation of the dependence of the pressure of the saturated vapor of the compounds in question on temperature were calculated; the boiling points of these compounds were calculated.

  3. 3.

    A graphic method of calculating the retention volume of unknown compounds in homologous series of bisarenechromium π complexes according to the boiling points of the corresponding aromatic hydrocarbons was offered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. G. A. Razuvaev, B. G. Gribov, G. A. Domrachev, and B. A. Salamatin, Organometallic Compounds in Electronics [in Russian], Nauka, Moscow (1972).

    Google Scholar 

  2. N. A. Vol'kenau, Methods of Heteroorganic Chemistry, π Complexes of Transition Metals with Arenes [in Russian], Nauka, Moscow (1976), p. 127.

    Google Scholar 

  3. G. G. Devyatykh, V. A. Umilin, Yu. B. Zverev, and I. A. Frolov, Izv. Akad. Nauk SSSR, Ser. Khim., 247 (1969).

  4. G. G. Devyatykh, V. A. Umilin, and Yu. B. Zverev, Izv. Akad. Nauk SSSR, Ser. Khim., 949 (1969).

  5. V. A. Umilin, Yu. B. Zverev, and I. I. Ermolaev, Izv. Akad. Nauk SSSR, Ser. Khim., 2726 (1971).

  6. T. L. Mironova, D. A. Vyakhirev, and A. M. Golubeva, Zh. Obshch. Khim.,44, 330 (1974).

    Google Scholar 

  7. A. N. Nesmeyanov, N. N. Zaitseva, G. A. Domrachev, V. D. Zinov'ev, L. P. Yur'eva, and I. I. Tverdokhlebova, J. Organomet. Chem.,121, C52 (1976).

    Google Scholar 

  8. A. D. Zorin, V. A. Umilin, and V. K. Vanchagova, Zavod. Lab.,40, 787 (1974).

    Google Scholar 

  9. A. I. Bruk, N. T. Karabanov, M. V. Nedoshivina, D. A. Vyakhirev, and É. P. Vetrova, Zh. Anal. Khim.,31, 1758 (1976).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. L. Ivanov, B. I. Kozyrkin, L. P. Yur'eva & N. N. Zaitseva

Authors
  1. L. L. Ivanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. I. Kozyrkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. P. Yur'eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. N. Zaitseva
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translatedfrom Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 855–860, April, 1980.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ivanov, L.L., Kozyrkin, B.I., Yur'eva, L.P. et al. GLC study of some physicochemical properties of dibenzenechromium and its alkyl derivatives. Russ Chem Bull 29, 608–612 (1980). https://doi.org/10.1007/BF00961613

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00961613

Keywords

Search

Navigation