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Estimation of the polar interaction between substituted nitrobenzenes and a nitrile stationary phase and some aspects of the use of the Hammett equation

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A new parameter A (δIi, j) is proposed which characterizes the polar (orientation, inductive, and specific) interactions between the substances passing through a Chromatograph and the stationary phase.

  2. 2.

    An equation is given for calculating the energy of the polar interaction from retention index values.

  3. 3.

    When nitrobenzenes with electron-accepting groups (Cl, Br, I, and NO2) are passed through a Chromatographic column containing a nitrile stationary phase, the parameter A (δIi,j) obeys the Hammett equation.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    Yu. N. Arsen'ev & R. V. Golovnya

Authors
  1. Yu. N. Arsen'ev
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  2. R. V. Golovnya
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Translated from Izvesiiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 851–854, April, 1980.

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Arsen'ev, Y.N., Golovnya, R.V. Estimation of the polar interaction between substituted nitrobenzenes and a nitrile stationary phase and some aspects of the use of the Hammett equation. Russ Chem Bull 29, 604–607 (1980). https://doi.org/10.1007/BF00961612

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  • DOI: https://doi.org/10.1007/BF00961612

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