Conclusions
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1.
The IR spectra of 1-methyl-substituted silacyclobutanes in inert-gas matrixes have been studied at 10°K (the tri- and hexadeuteromethyl derivatives were prepared and studied for the first time).
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2.
The frequencies of the vibrations characterizing the silacyclobutane ring have been refined, and the changes in the intensities of the bands and the vibrational frequencies of the Si-CH3 group on deutero substitution have been determined.
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We thank V. T. Aleksanyan for valuable comments and discussion of the spectra obtained.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 837–844, April, 1980.
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Khabashesku, V.N., Mal'tsev, A.K. & Nefedov, O.M. IR spectra of silacyclobutanes in Ar matrix at 10°K. Russ Chem Bull 29, 591–597 (1980). https://doi.org/10.1007/BF00961609
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DOI: https://doi.org/10.1007/BF00961609