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Mechanism of the Z, E isomerization of α-nitro-β-phenylaminoacrylate

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Study of the kinetics of the Z, E isomerization of α-nitro-β-phenylaminoacrylate ester in a solvating medium by NMDR shows that the reaction is initiated by the solvent, and kinetically is first-order.

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Literature cited

  1. V. I. Bakhmutov, V. A. Burmistrov, K. K. Babievskii, V. M. Belikov, and É. I. Fedin Izv. Akad. Nauk. SSSR, Ser. Khim., 2820 (1977).

  2. H. Kalinowski and H. Kessler, Topics in Stereochem.,7, 296 (1973).

    Google Scholar 

  3. V. I. Bakhmutov, V. A. Burmistrov, K. K. Babievskii, É. I. Fedin, and V. M. Belikov Izv. Akad. Nauk SSSR, Ser. Khim., 2601 (1977).

  4. U. Shmueli, H. Shanan-Atidi, H. Horwitz, and I. Shvo, J. Chem. Soc. Perkin Trans. 2, 657 (1973).

    Google Scholar 

  5. W. Schwotzer and W. Pilipsborn, Helv. Chim. Acta,60, 1501 (1977).

    Google Scholar 

  6. E. Kleinpeter and M. Pulst, Org. Magn. Reson.,9, 308 (1977).

    Google Scholar 

  7. B. I. Ionin and B. A. Ershov, NMR Spectroscopy in Organic Chemistry [in Russian] Khimiya (1967), p. 285.

  8. J. Frank, P. Dvortsak, G. Horwath, Z. Meszaros, and G. Toth, Acta Chim. Acad, Scient. Hung.,89, 91 (1976).

    Google Scholar 

  9. J. T. Arnold, Phys. Rev.,102, 136 (1956).

    Google Scholar 

  10. J. A. Riddick and W. B. Bunger, Organic Solvents, Wiley-Interscience, New York (1971).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. I. Bakhmutov, V. A. Burmistrov & K. A. Kochetkov

Authors
  1. V. I. Bakhmutov
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  2. V. A. Burmistrov
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  3. K. A. Kochetkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 829–833, April, 1980.

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Bakhmutov, V.I., Burmistrov, V.A. & Kochetkov, K.A. Mechanism of the Z, E isomerization of α-nitro-β-phenylaminoacrylate. Russ Chem Bull 29, 582–585 (1980). https://doi.org/10.1007/BF00961607

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  • DOI: https://doi.org/10.1007/BF00961607

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