Conclusions
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1.
The rate constant for thermal rupture of the peroxide bond in dicyclohexylperoxydicarbonate has been determined from the reaction kinetics which apply under conditions minimizing the effect of chain reaction components.
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2.
Dicyclohexylperoxydicarbonate and benzoyl peroxide react stoichiometrically to form N,N'-di-β-naphthyl-p-phenylenediamine. A colorimetric method is proposed for quantitatively determining peroxides at low concentrations (10−5 mole/liter).
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Z. S. Kartasheva, A. B. Gargarina, and N. M. Émanuél', Dokl. Akad. Nauk SSSR,212, 134 (1973).
N. V. Zolotova and E. T. Denisov, Zh. Fiz. Khim.,46, 2008 (1972).
E. T. Denisov and R. L. Vardanyan, Izv. Akad. Nauk SSSR, Ser. Khim., 2463 (1972).
L. N. Denisova, E. T. Denisov, and D. I. Metelitsa, Zh. Fiz. Khim.,44, 1670 (1970).
D. G. Pobedimskii, A. L. Buchachenko, and M. B. Neiman, Zh. Fiz. Khim.,42, 1436 (1968).
L. Horner, J. Polym. Sci.,18, 438 (1955).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 790–794, April, 1980.
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Kartasheva, Z.S., Gargarina, A.B. Use of a colorimetric method of peroxide analysis for determining the rate constant for homolytic rupture of the peroxide bond in dicyclohexylperoxydicarbonate. Russ Chem Bull 29, 543–547 (1980). https://doi.org/10.1007/BF00961599
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DOI: https://doi.org/10.1007/BF00961599