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Nature of oxidation waves on polarograms of solutions of nitrites in nonaqueous media

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The oxidation wave on the polarograms of nitrites in protic and aprotic organic media is due to enhancement of the process of ionization of mercury on account of combination of Hg2+ ions into a complex with NO2 − ions. The number of ligands in the complex is two.

  2. 2.

    In principle, it is possible to make a quantitative determination of NO2 − ions in nonaqueous protic or aprotic solvents.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    F. M. Rafikov & V. A. Petrosyan

Authors
  1. F. M. Rafikov
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  2. V. A. Petrosyan
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 749–754, April, 1980.

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Rafikov, F.M., Petrosyan, V.A. Nature of oxidation waves on polarograms of solutions of nitrites in nonaqueous media. Russ Chem Bull 29, 505–509 (1980). https://doi.org/10.1007/BF00961591

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  • DOI: https://doi.org/10.1007/BF00961591

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