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Mechanism of the hydroamination of alcohols and carbonyl compounds on a fused iron catalyst

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

In a study of the reaction of 2,2-dimethyl-1-propanol, 2-ethyl-1-hexanol, 2-octanol, and 4-heptanol or 4-heptanone and 2-octanone with aminating agents such as ammonia, dimethylamine, and propylamine in the presence of hydrogen on a fused iron catalyst, we showed that the desired amines are formed through both “imine” and “enamine” mechanisms.

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Literature cited

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    G. A. Kliger, A. N. Shuikin, L. S. Glebov, A. I. Mikaya, S. M. Loktev & V. G. Zaikin

Authors
  1. G. A. Kliger
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  2. A. N. Shuikin
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  3. L. S. Glebov
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  4. A. I. Mikaya
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  5. S. M. Loktev
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  6. V. G. Zaikin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1923–1926, August, 1990.

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Kliger, G.A., Shuikin, A.N., Glebov, L.S. et al. Mechanism of the hydroamination of alcohols and carbonyl compounds on a fused iron catalyst. Russ Chem Bull 39, 1750–1753 (1990). https://doi.org/10.1007/BF00961521

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  • DOI: https://doi.org/10.1007/BF00961521

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