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Radical telomerization of vinyltrimethylsilane with diethyl phosphite

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Telomerization of vinyltrimethylsilane with diethyl phosphite was carried out in the presence of tert-butyl peroxide (TBP), affording a series of regular telomers (EtO)2P(O)(CH2CHSiMe3)nH (n=1–3)(Tn) and the compounds Me3Si· (CH2)2CH(CH3)OP(O)(OEt)(CH2)2SiMe3(T2′). Arguments are presented which support a rearrangement with 1,5-H migration in the first propagating radical along a chain including P and O atoms. The partial chain-transfer constant C1 (6.2) was evaluated.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    M. A. Moskalenko & A. B. Terent'ev

Authors
  1. M. A. Moskalenko
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  2. A. B. Terent'ev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1883–1887, August, 1990.

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Moskalenko, M.A., Terent'ev, A.B. Radical telomerization of vinyltrimethylsilane with diethyl phosphite. Russ Chem Bull 39, 1711–1715 (1990). https://doi.org/10.1007/BF00961507

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  • DOI: https://doi.org/10.1007/BF00961507

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