Skip to main content
SpringerLink
Log in

Reaction of nitrosonium trifluoromethanesulfonate with fluoroolefins and some properties of the resulting products

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The reaction of nitrosonium trifluoromethanesulfonate with fluoroolefins resulted in β-nitrosofluoroalkyltrifluoromethanesulfonates, the corresponding 1,2-oxazetidines, and nitrosofluoro polymers. The nitroso compounds, under the effect of nitrogen tetroxide, were oxidized to β-nitrofluoroalkyltrifluoromethanesulfonates. Pyrolysis of the oxazetidines and nitrosofluoro polymers resulted in the synthesis of fluoroazomethines containing the CF3-SO2O group.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, and V. G. Chilikin, Izv. Akad. Nauk SSSR, Ser. Khim., No. 5, 1196 (1984).

    Google Scholar 

  2. A. V. Fokin, A. I. Rapkin, V. G. Chilikin, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 4, 891 (1986).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelemental Compounds, Academy of Sciences of the USSR, Moscow

    V. S. Savostin, I. I. Krylov, A. P. Kutepov, A. I. Rapkin & A. V. Fokin

Authors
  1. V. S. Savostin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. I. Krylov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. P. Kutepov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. I. Rapkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. V. Fokin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1851–1855, August, 1990.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Savostin, V.S., Krylov, I.I., Kutepov, A.P. et al. Reaction of nitrosonium trifluoromethanesulfonate with fluoroolefins and some properties of the resulting products. Russ Chem Bull 39, 1681–1684 (1990). https://doi.org/10.1007/BF00961501

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00961501

Keywords

Search

Navigation