Abstract
Perfluoro(alkoxycyclopropanes) are isomerized on heating in the presence of SbF5 into perfluoro(2-alkoxypropylenes), while perfluoro(alkylcyclopropanes) are isomerized into the corresponding internal fluoroolefins under the effect of SbF5.
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M. V. Galakhov, V. A. Petrov, V. I. Bakhmutov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 2, 306 (1985).
V. A. Petrov, G. G. Belen'kii, M. V. Galakhov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 12, 2811 (1984).
P. R. Shleyer, M. Sounders, and J. C. Rosenfeld, J. Am. Chem. Soc.,91, 5174 (1969).
J. M. Birchall, R. Fields, and R. N. Haszeldine, J. Chem. Soc. Perkin Trans.1, 1773 (1973).
H. N. C. Wong, M. J. Hon, C. W. Tse, et al., Chem. Rev.,89, 187 (1989).
B. E. Smart, in: The Chemistry of Functional Groups, S. Patai and Z. Rappaport (eds.), Wiley, New York (1983).
G. G. Belen'kii and L. S. German, Sov. Sci. Rew., Sec. B, Chem. Rew.,5, 206 (1984).
P. B. Sargeant, J. Org. Chem.,35, 678 (1970).
M. V. Galakhov, V. A. Petrov, G. G. Belen'kii, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 6, 1054 (1986).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1844–1851, August, 1990.
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Chepik, S.D., Petrov, V.A., Galakhov, M.V. et al. Electrophilic isomerization of substituted perfluorocyclopropanes under the effect of SbF5 . Russ Chem Bull 39, 1674–1680 (1990). https://doi.org/10.1007/BF00961500
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DOI: https://doi.org/10.1007/BF00961500