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Interphase analysis in the chemistry of aliphatic nitro compounds. 1. Alkylation of alkali metal salts of trinitromethane under interphase catalysis conditions in solid phase-liquid systems

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Methylation of trinitromethane salts was studied under interphase catalysis conditions in a solid phase (a trinitromethane salt)-liquid (methyl iodide) system in the presence of interphase transfer catalysts — onium salts, cyclic and acyclic polyethers. The dependence of the yield of the methylation product-1,1,1-trinitroethane — on the nature of the catalyst was also investigated, and based on this, catalysts were found, in whose presence the methylation process is realized more effectively than under homogeneous conditions.

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Literature cited

  1. V. I. Erashko, S. A. Shevelev, and A. A. Fainzil'berg, Usp. Khim.,35, 1740 (1966).

    Google Scholar 

  2. O. P. Beletskaya, O. A. Reutov, K. P. Butin, et al., CH-Acids [in Russian], Khimiya, Moscow (1980).

    Google Scholar 

  3. S. A. Shevelev, V. I. Erashko, and A. A. Fainzil'berg, Izv. Akad. Nauk SSSR, Ser. Khim., No. 12, 2725 (1976).

    Google Scholar 

  4. Z. Demlov and E. Demlov, Interphase Analysis [Russian translation], Mir, Moscow (1987).

    Google Scholar 

  5. A. P. Khmel'nitskii and E. G. Lubenets, Zh. Vses. Khim. O-va,31, No. 2, 203 (1986).

    Google Scholar 

  6. D. J. Glover and M. J. Kamlet, J. Org. Chem.,26, 4734 (1961).

    Google Scholar 

  7. S. S. Yufit, I. A. Esikova, and O. I. Danilova, Dokl. Akad. Nauk SSSR,295, No. 3, 621 (1987).

    Google Scholar 

  8. F. Bogart, A. Seeler, and P. Noble, J. Org. Chem.,31, 2806 (1966).

    Google Scholar 

  9. G. S. Hammond, W. D. Emmons, C. Parker, et al., Tetrahedron,19, Suppl. 1, 177 (1963).

    Google Scholar 

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1816–1819, August, 1990.

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Shevelev, S.A., Dalinger, L.I., Vinogradov, V.M. et al. Interphase analysis in the chemistry of aliphatic nitro compounds. 1. Alkylation of alkali metal salts of trinitromethane under interphase catalysis conditions in solid phase-liquid systems. Russ Chem Bull 39, 1647–1650 (1990). https://doi.org/10.1007/BF00961495

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  • DOI: https://doi.org/10.1007/BF00961495

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