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Synthesis on the basis of electrogenerated carbenes. 8. Formation of dibromo-, bromochloro-, and dichlorocarbenes by the cathode electrolysis of tetrabromomethane

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Dibromocarbene generated by the cathodic reduction of CBr4 reacts with cyclohexene or trimethylethylene with the formation of dibromocyclopropane derivatives; it can also enter into exchange processes with the chloride ion, which is present in solution, leading to bromochloro- and dichlorocarbenes. The reaction of these with olefins leads to the formation of the corresponding bromochloro- and dichlorocyclopropanes.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    M. E. Niyazymbetov, T. Yu. Rudashevskaya, L. V. Adaevskaya & V. A. Petrosyan

Authors
  1. M. E. Niyazymbetov
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  2. T. Yu. Rudashevskaya
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  3. L. V. Adaevskaya
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  4. V. A. Petrosyan
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1802–1806, August, 1990.

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Niyazymbetov, M.E., Rudashevskaya, T.Y., Adaevskaya, L.V. et al. Synthesis on the basis of electrogenerated carbenes. 8. Formation of dibromo-, bromochloro-, and dichlorocarbenes by the cathode electrolysis of tetrabromomethane. Russ Chem Bull 39, 1633–1637 (1990). https://doi.org/10.1007/BF00961492

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  • DOI: https://doi.org/10.1007/BF00961492

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