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Study of nitration equilibrium in the glycerin-aqueous nitric acid system. 2. Changes in δH and δS in the nitration reaction

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The real enthalpies of seven sequential-parallel reactions of nitration of glycerin into glycerin trinitrate were found by combination of the heats of the reactions obtained by the thermochemical method and with the equation for the isobar of the chemical reaction, and the standard enthalpies of formation of glycerin nitrates were calculated with them. The difference in the enthalpies of nitration with respect to different positions in glycerin and its nitrates basically determines the difference in the corresponding equilibrium constants of the nitration reactions.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    A. I. Kazakov, E. P. Kirpichev, G. V. Lagodzinskaya, L. P. Andrienko, N. G. Yunda, A. M. Korolev, Yu. I. Rubtsov, G. B. Manelis & L. T. Eremenko

Authors
  1. A. I. Kazakov
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  2. E. P. Kirpichev
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  3. G. V. Lagodzinskaya
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  4. L. P. Andrienko
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  5. N. G. Yunda
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  6. A. M. Korolev
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  7. Yu. I. Rubtsov
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  8. G. B. Manelis
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  9. L. T. Eremenko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1729–1734, August, 1990.

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Kazakov, A.I., Kirpichev, E.P., Lagodzinskaya, G.V. et al. Study of nitration equilibrium in the glycerin-aqueous nitric acid system. 2. Changes in δH and δS in the nitration reaction. Russ Chem Bull 39, 1565–1570 (1990). https://doi.org/10.1007/BF00961478

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  • DOI: https://doi.org/10.1007/BF00961478

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