Abstract
Unlike the iron-modified pentasil, the ferrisilicate has high heterocyclizing activity in the formation of 2-methylthiophene from hydrogen sulfide and n-pentane. During the reaction and the subsequent regenerations a considerable proportion of iron ions leaves the ferrisilicate lattice. The heterocyclizing activity is probably related to the formation of a highly dispersed Fe sulfide phase in the zeolite channels.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1713–1717, August, 1990.
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Ryashentseva, M.A., Belanova, E.P., Minachev, K.M. et al. Heterocyclizing properties of ferrisilicate in the reaction of n-pentane with hydrogen sulfide. Russ Chem Bull 39, 1551–1555 (1990). https://doi.org/10.1007/BF00961475
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DOI: https://doi.org/10.1007/BF00961475