Synthesis and conversions of metallocycles. 7. A novel approach to the synthesis of 3,4-dialkyl-substituted aluminacyclopentanes in the presence of Cp2ZrCl2

  • U. M. Dzhemilev
  • A. G. Ibragimov
  • A. B. Morozov
  • R. R. Muslukhov
  • G. A. Tolstikov
Organic Chemistry

Abstract

A novel approach was developed for the stereoselective synthesis of trans-3,4-dialkyl-substituted aluminacyclopentanes from α-olefins, metallic magnesium, and EtAlCl2 in the presence of catalytic amounts of Cp2ZrCl2. The hydrolysis and deuterolysis products of the 3,4-dialkyl-substituted aluminacyclopentanes obtained are only in the trans configuration.

Keywords

Hydrolysis Magnesium Catalytic Amount Trans Configuration Stereoselective Synthesis 

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Literature cited

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    U. M. Dzhemilev, A. G. Ibragimov, A. B. Morozov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 5, 1141 (1991).Google Scholar
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Copyright information

© Plenum Publishing Corporation 1992

Authors and Affiliations

  • U. M. Dzhemilev
    • 1
  • A. G. Ibragimov
    • 1
  • A. B. Morozov
    • 1
  • R. R. Muslukhov
    • 1
  • G. A. Tolstikov
    • 1
  1. 1.Institute of Chemistry, Bashkir Scientific Center, Ural BranchAcademy of Sciences of the USSRUfa

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