Structure of 2-chloromethyl-2λ5-2,2′(3h,3′h)-spirobis[1,3,2- benzoxazaphosphole]

  • A. N. Chekhlov
  • A. N. Bovin
  • E. N. Tsvetkov
Physical Chemistry

Abstract

In 2-chloromethyl-2λ5-2,2′(3H,3′H)-spirobis[1,3,2-benzoxazaphosphole], which has been investigated by x-ray diffraction, the P atom has a distorted trigonal-bipyramidal coordination with O atoms in axial positions; the angle between the two planes of the 3H-1,3,2-benzoxazaphosphole fragments is 128.8°.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    V. A. Naumov and L. V. Vilkov, Molecular Structures of Organophosphorus Compounds [in Russian], Nauka, Moscow (1986).Google Scholar
  2. 2.
    P. F. Meunier, R. O. Day, J. R. Devillers, and R. R. Holmes, Inorg. Chem.,17, 3270 (1978).Google Scholar
  3. 3.
    F. H. Allen, O. Kennard, D. G. Watson, et al., J. Chem. Soc., Perkin Trans. 2, No. 12, S1-S19 (1987).Google Scholar
  4. 4.
    A. N. Chekhlov, S. P. Ionov, A. N. Bovin, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2240 (1985).Google Scholar

Copyright information

© Plenum Publishing Corporation 1991

Authors and Affiliations

  • A. N. Chekhlov
    • 1
  • A. N. Bovin
    • 1
  • E. N. Tsvetkov
    • 1
  1. 1.Institute of Physiologically Active SubstancesAcademy of Sciences of the USSRChernogolovka

Personalised recommendations