Spectroscopic study of the conformation of 1,3,2-dioxaphosphorinanes with a P=S bond

  • I. Kh. Shakirov
  • R. R. Shagidullin
  • R. P. Arshinova
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Abstract

5,5- Dimethyl-2-thio-2-phenoxy- and 5,5-dimethyl-2-thio-2-ethoxy-1,3,2-dioxaphosphorinanes exist in the liquid state and in solution in a three-component equilibrium featuring two chair forms with equatorial orientation of the P=S bond differing in the orientation of the OPh or OEt groups and a chair form with an axial P=S bond. The P=S bond in 4-methyl-2-thio-2-phenoxy-1,3,2-dioxaphosphorinane occupies the equatorial position.

Keywords

Liquid State Spectroscopic Study Equatorial Position Equatorial Orientation Chair Form 

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Literature cited

  1. 1.
    I. Kh. Shakirov and R. R. Shagidullin, Zh. Obshch. Khim.,48, 508 (1978).Google Scholar
  2. 2.
    R. R. Shagidullin, I. Kh. Shakirov, R. Kh. Musyakaeva, and I. A. Nuretdinov, Izv. Akad. Nauk SSSR, Ser. Khim., 1890 (1981).Google Scholar
  3. 3.
    R. R. Shagidullin, I. Kh. Shakirov, A. Kh. Plyamovatyi, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2517 (1984).Google Scholar
  4. 4.
    A. Kh. Plyamovatyi, R. R. Shagidullin, I. Kh. Shakirov, and R. P. Arshinova, Izv. Akad. Nauk SSSR, Ser. Khim., 92 (1987).Google Scholar
  5. 5.
    R. P. Arshinova, T. D. Sorokina, A. B. Remizov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2242 (1979).Google Scholar
  6. 6.
    B. A. Arbuzov, R. R. Shagidullin, I. Kh. Shakirov, et al., Zh. Obshch. Khim.,56, 1029 (1986).Google Scholar

Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • I. Kh. Shakirov
    • 1
  • R. R. Shagidullin
    • 1
  • R. P. Arshinova
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan BranchAcademy of Sciences of the USSRUSSR

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