Reaction of phosphorus trichloride with carboxylic acids

  • L. A. Valitova
  • E. V. Popova
  • Sh. N. Ibragimov
  • B. E. Ivanov
Organic Chemistry

Abstract

The reaction of phosphorus trichloride with a number of monobasic carboxylic acids has been studied and the optimum ratio of reactants for the yield of acid chlorides has been established. Based on analysis and the data from31P NMR spectroscopy of the phosphorus-containing products from this reaction it is shown that at 402-50°C a mixture of P-H acids having a predominant content of pyrophosphorous acid is formed.

Keywords

Spectroscopy Chloride Phosphorus Carboxylic Acid Acid Chloride 

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Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • L. A. Valitova
    • 1
  • E. V. Popova
    • 1
  • Sh. N. Ibragimov
    • 1
  • B. E. Ivanov
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan BranchAcademy of Sciences of the USSRUSSR

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