Quenching of singlet oxygen by alkenes with a hindered double bond

  • G. L. Sharipov
  • A. I. Voloshin
  • V. P. Kazakov
  • G. A. Tolstikov
Physical Chemistry
  • 25 Downloads

Abstract

Both the chemical reaction of oxidation and the physical deactivation of1O2 caused by the dimension of the exciting energy in vibrations of the C-H bonds of the molecule of the quenching agent play an important role in quenching of singlet oxygen by substituted adamantylidenenorbornanes with a hindered double bond. The substituents which shield the double bond have a stereoelectronic effect on the reaction of 1,2-cycloaddition of singlet oxygen. The almost total inhibition of the oxidation reaction is possible as a function of their position.

Keywords

Oxidation Oxygen Double Bond Alkene Oxidation Reaction 

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Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • G. L. Sharipov
    • 1
  • A. I. Voloshin
    • 1
  • V. P. Kazakov
    • 1
  • G. A. Tolstikov
    • 1
  1. 1.Institute of Chemistry, Bashkir Scientific Center, Ural BranchAcademy of Sciences of the USSRUfa

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