Formation of a paramagnetic complex from the bischelate of palladium(II) with dehydrogenated N-(3-hydroximino-2-methylbutyl-2)hydroxylamine and o-phenanthroline

  • L. A. Kosareva
  • E. G. Boguslavskii
  • S. V. Larionov
Inorganic Chemistry
  • 26 Downloads

Abstract

The reaction in absolute ethanol of σ-phenanthroline and the diamagnetic bischelate of palladium(II) containing anions of dehydrogenated N-(3-hydroximino-2-methylbutyl-2)hydroxylamine yields a paramagnetic palladium(II) complex which contains a coordinated anion-radical of dehydrogenated 1,2-hydroxylaminooxime.

Keywords

Palladium Absolute Ethanol Hydroxylamine Paramagnetic Complex Paramagnetic Palladium 

Literature cited

  1. 1.
    S. V. Larionov, Noble Metals: Chemistry and Technology. Collection of Scientific Works, [in Russian], Akad. Nauk SSSR, Sib. Otd. Inst. Neorg. Khim. Novosibirsk (1989), pp. 164–185.Google Scholar
  2. 2.
    S. V. Larionov, L. A. Kosareva, and E. G. Boguslavskii, Izv. Akad. Nauk SSSR, Ser. Khim., No. 11, oo2592 (1984).Google Scholar
  3. 3.
    S. V. Larionov, L. A. Kosareva, and E. G. Boguslavskii, Izv. Akad. Nauk SSSR, Ser. Khim., No. 9, 2110 (1986).Google Scholar

Copyright information

© Plenum Publishing Corporation 1992

Authors and Affiliations

  • L. A. Kosareva
    • 1
  • E. G. Boguslavskii
    • 1
  • S. V. Larionov
    • 1
  1. 1.Institute of Inorganic Chemistry, Siberian BranchAcademy of Sciences of the USSRNovosibirsk

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