Abstract
The addition of morpholino-, piperidino-, and N,N-diethyldithiocarbamate anions to 1,2-propadiene- and 1,2-butadienephosphonates proceeds on the electrophilic 1,2-double bond of the allene system with the formation of linear dithioesters. 1-Vinylallenylphosphonates add dithiocarbamate anions on the 1,3-conjugated system of multiple bonds, forming a mixture of stereoisomeric dithioesters with a diene structure.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 890–894, April, 1990.
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Khusainova, N.G., Suppel', I.Y., Cherkasov, R.A. et al. Reactions of phosphorylated allenes with dithiocarbamates. Russ Chem Bull 39, 798–802 (1990). https://doi.org/10.1007/BF00960349
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DOI: https://doi.org/10.1007/BF00960349