Reactions of phosphorylated allenes with dithiocarbamates

  • N. G. Khusainova
  • I. Ya. Suppel'
  • R. A. Cherkasov
  • A. N. Pudovik
Organic Chemistry

Abstract

The addition of morpholino-, piperidino-, and N,N-diethyldithiocarbamate anions to 1,2-propadiene- and 1,2-butadienephosphonates proceeds on the electrophilic 1,2-double bond of the allene system with the formation of linear dithioesters. 1-Vinylallenylphosphonates add dithiocarbamate anions on the 1,3-conjugated system of multiple bonds, forming a mixture of stereoisomeric dithioesters with a diene structure.

Keywords

Diene Dithiocarbamate Morpholino Multiple Bond Allene System 

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Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • N. G. Khusainova
    • 1
  • I. Ya. Suppel'
    • 1
  • R. A. Cherkasov
    • 1
  • A. N. Pudovik
    • 1
  1. 1.V. I. Ul'yanov-Lenin Kazan State UniversityUSSR

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