Mass spectrometric study of dimethyl-substituted spiro[4.5]decanes and spiro[5.5]undecanes

  • G. V. Rusinova
  • L. S. Golovkina
  • N. B. Novikova
  • I. M. Sokolova
  • Al. A. Petrov
Physical Chemistry
  • 21 Downloads

Conclusions

  1. 1.

    A study has been made of the mass spectra of dimethyl-substituted hydrocarbons in the spiro[4.5]decane and spiro[5.5]undecane series, and it has been shown that the character of decomposition of their molecular ions is determined mainly by the relative positions of the spiro atom and the substituted carbon atoms in the molecule.

     
  2. 2.

    A criterion has been proposed for identifying the structural isomers of spiro[4.5]-decanes and spiro[5.5]undecanes.

     
  3. 3.

    The mass spectra of the stereoisomers generally do not contain any diagnostic differences.

     

Keywords

Mass Spectrum Hydrocarbon Carbon Atom Relative Position Decane 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    N. B. Novikova, I. M. Sokolova, and L. I. Soboleva, Neftekhimiya,26, 499 (1986).Google Scholar
  2. 2.
    N. B. Novikova, I. M. Sokolova, and Al. A. Petrov, Neftekhimiya,24, 766 (1984).Google Scholar
  3. 3.
    N. B. Novikova, I. M. Sokolova, T. I. Pekhk, and Al. A. Petrov, Neftekhimiya,26, No. 3 (1986).Google Scholar
  4. 4.
    L. S. Golovkina, G. V. Rusinova, and Al. A. Petrov, Usp. Khim.,53, 1493 (1984).Google Scholar

Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • G. V. Rusinova
    • 1
  • L. S. Golovkina
    • 1
  • N. B. Novikova
    • 1
  • I. M. Sokolova
    • 1
  • Al. A. Petrov
    • 1
  1. 1.Institute of Geology and Development of Fossil FuelsMinistry of the Petroleum Industry and Academy of Sciences of the USSRMoscow

Personalised recommendations