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Formation of aminotetrazines and triazoles by alkaline hydrolysis of thiosemicarbazide

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

3,6-Diamino-1,2,4,5-tetrazine is formed by alkaline hydrolysis of thiosemicarbazide in the presence of oxidizing agents (oxygen, silver ions). 3,4,5-Triamino-1, 2,4-triazole is formed when the temperature is raised and when oxidizing agents are absent.

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Authors and Affiliations

  1. S. M. Kirov Ural Polytechnic Institute, Sverdlovsk

    A. B. Katunina, E. G. Kovalev & G. A. Kitaev

Authors
  1. A. B. Katunina
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  2. E. G. Kovalev
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  3. G. A. Kitaev
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 847–849, June, 1975.

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Katunina, A.B., Kovalev, E.G. & Kitaev, G.A. Formation of aminotetrazines and triazoles by alkaline hydrolysis of thiosemicarbazide. Chem Heterocycl Compd 11, 743–745 (1975). https://doi.org/10.1007/BF00959977

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  • DOI: https://doi.org/10.1007/BF00959977

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