Reaction of elemental phosphorus with phenols

  • B. E. Ivanov
  • E. K. Badeeva
  • S. S. Krokhina
Brief Communications

Conclusions

The composition and yield of the products formed upon the reaction of elemental phosphorus with phenols depends on the acidity of the phenol and the nature of the ring substituent. The phenol pKa range, in which the reaction of elemental phosphorus with phenols is possible, is 9–11.

Keywords

Phosphorus Phenol Acidity Elemental Phosphorus Ring Substituent 

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Literature cited

  1. 1.
    German Democratic Republic Patent No. 152,132; Chem. Abstr.,97, 324008n (1982).Google Scholar
  2. 2.
    C. Brown, R. F. Hudson, G. A. Wartew, and H. Coates, Phosphorus Sulfur,6, 481 (1979).Google Scholar
  3. 3.
    S. I. Vol'fkovich, V. K. Kuskov, and K. F. Koroteeva, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, 5 (1954).Google Scholar
  4. 4.
    C. Brown R. F. Hudson, and G. A. Wartew, Phosphorus Sulfur,5, 121 (1978).Google Scholar
  5. 5.
    M. Hiraoka, Studies in Organic Chemistry, Vol. 12: Crown Compounds. Their Characteristics and Applications, Elsevier, Amsterdam (1982).Google Scholar
  6. 6.
    F. G. Williams and P. E. Donahue, J. Org. Chem.,42, 3414 (1977).Google Scholar
  7. 7.
    G. M. Kosolapoff and L. Maier (eds.), Organic Phosphorus Compounds, Vol. 6, New York (1973), p. 410.Google Scholar
  8. 8.
    M. M. Crutchfield, C. H. Dungan, G. H. Letcher, et al., Topics in Phosphorus Chemistry, Vol. 5, Interscience Publ., New York-London-Sydney (1967), p. 263.Google Scholar

Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • B. E. Ivanov
    • 1
  • E. K. Badeeva
    • 1
  • S. S. Krokhina
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan BranchAcademy of Sciences of the USSRUSSR

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