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Homodimerization of spiro{bicyclo[2.2.1]Hepta-2,5-Diene-7,1′-cyclopropane}, catalyzed by group VIII transition metal complexes

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The homodimerization of spiro{bicyclo[2.2.1]hepta-2,5-diene-7,1′-cyclopropane} (I) has been investigated in the presence of Ni-, Fe-, Co-, Rh-, and Ir-based metal complex catalysts. Depending on the nature of the metal and its ligand environment cyclodimerization of (I) can take place via [2π+2π]-, [2π+2π+2π]-, and [4π+4π]-cycloaddition schemes, to give high yields of hepta-, octa-, and nonacyclic strained hydrocarbons.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Scientific Center, Urals Branch, Academy of Sciences of the USSR, Ufa

    U. M. Dzhemilev, R. I. Khusnutdinov, Z. S. Muslimov, O. M. Nefedov & G. A. Tolstikov

Authors
  1. U. M. Dzhemilev
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  2. R. I. Khusnutdinov
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  3. Z. S. Muslimov
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  4. O. M. Nefedov
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  5. G. A. Tolstikov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2592–2599, November, 1988.

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Dzhemilev, U.M., Khusnutdinov, R.I., Muslimov, Z.S. et al. Homodimerization of spiro{bicyclo[2.2.1]Hepta-2,5-Diene-7,1′-cyclopropane}, catalyzed by group VIII transition metal complexes. Russ Chem Bull 37, 2337–2343 (1988). https://doi.org/10.1007/BF00959891

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  • DOI: https://doi.org/10.1007/BF00959891

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