Conclusions
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1.
An efficient method of aziridine dimer synthesis is presented involving reaction of aziridine with esters of strong organic acids followed by alkaline hydrolysis of the resultant N-acyl derivatives.
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2.
New N-acyl and carbamoyl derivatives of aziridine dimer and trimer were synthesized.
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3.
Linear and branched isomers of aziridine tetramer and also diastereomers of 2-methylaziridine dimer were isolated and characterized.
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4.
An efficient regiospecific synthesis of 2,2-dimethylaziridine dimer and trimer was developed.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2566–2575, November, 1988.
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Kostyanovskii, R.G., Leshchinskaya, V.P., Alekperov, R.K. et al. Oligomers of aziridines and N-β-aziridinoethylamides. Russ Chem Bull 37, 2315–2323 (1988). https://doi.org/10.1007/BF00959886
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DOI: https://doi.org/10.1007/BF00959886