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Chemistry of 1,1,2,2-tetracyanoethane. 12. Condensation of 1,1,2,2-tetracyanoethane with crotonaldehyde in alcoholic solution

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Condensation of 1,1,2,2-tetracyanoethane with crotonaldehyde and the solvent (alcoholic medium) takes place in the ratio 1∶2∶1 to give 2-amino-5-methyl-3-(1-methyl-3-alkoxyallyl)-1-formyl-3, 4,4-tricyanoyclopentenes.

  2. 2.

    On the basis of an x-ray diffraction analysis of the product with an isopropoxy-group in the 3-position, the main features of its molecular structure are discussed, and a stepwise route is proposed for the reaction and its stereochemical features examined.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    A. B. Zolotoi, S. P. Zil'berg, P. M. Lukin, S. V. Konovalikhin, O. E. Nasakin, A. N. Lyshchikov, O. A. D'yachenko, A. Kh. Bugai, L. O. Atovmyan & M. Yu. Skvortsova

  2. N. I. Ulyanov Chebokarsk State University, USSR

    A. B. Zolotoi, S. P. Zil'berg, P. M. Lukin, S. V. Konovalikhin, O. E. Nasakin, A. N. Lyshchikov, O. A. D'yachenko, A. Kh. Bugai, L. O. Atovmyan & M. Yu. Skvortsova

Authors
  1. A. B. Zolotoi
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  2. S. P. Zil'berg
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  3. P. M. Lukin
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  4. S. V. Konovalikhin
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  5. O. E. Nasakin
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  6. A. N. Lyshchikov
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  7. O. A. D'yachenko
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  8. A. Kh. Bugai
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  9. L. O. Atovmyan
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  10. M. Yu. Skvortsova
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Additional information

For previous communication, see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2561—2566, November, 1988.

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Zolotoi, A.B., Zil'berg, S.P., Lukin, P.M. et al. Chemistry of 1,1,2,2-tetracyanoethane. 12. Condensation of 1,1,2,2-tetracyanoethane with crotonaldehyde in alcoholic solution. Russ Chem Bull 37, 2311–2314 (1988). https://doi.org/10.1007/BF00959885

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  • DOI: https://doi.org/10.1007/BF00959885

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