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Replacement of halogen in α-halonitro-compounds of the aliphatic series. 3. Preparation and properties of sodium salts of esters of nitrosulfoacetic acid

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of esters of chloro- and bromonitroacetic acids (I) with NaHSO3, Na2SO3, and Na2S2O4, has resulted in the formation of Na-salts of esters of nitrosulfoacetic acid.

  2. 2.

    In the reaction of (I) with Na2SO3 and a double quantity of NaHCO3, Na-salts of esters of halonitroacetic acid are formed, and the reaction of (I) with Na2S2O4 and NaHCO3 leads to Na-salts of esters of sulfoacetic acid.

  3. 3.

    Physicochemical methods have been used to determine the spectroscopic characteristics and pKa of sodium salts of esters of nitrosulfoacetic acids and their low toxicity has been established.

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Authors and Affiliations

  1. Institute for Physiologically Active Substances, Academy of Sciences of the USSR, Chernogolovka

    A. I. Yurtanov, A. V. Yarkov, T. I. Ignat'eva, V. O. Zavel'skii, B. K. Beznosko, O. V. Novikova, V. N. Semyonova & I. V. Martynov

Authors
  1. A. I. Yurtanov
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  2. A. V. Yarkov
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  3. T. I. Ignat'eva
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  4. V. O. Zavel'skii
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  5. B. K. Beznosko
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  6. O. V. Novikova
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  7. V. N. Semyonova
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  8. I. V. Martynov
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Additional information

For previous communications, see [1, 2].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2549–2556, November, 1988.

The authors are grateful to V. I. Kozlovskii for running the chromatography-mass spectrometry analyses of the gas mixtures.

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Yurtanov, A.I., Yarkov, A.V., Ignat'eva, T.I. et al. Replacement of halogen in α-halonitro-compounds of the aliphatic series. 3. Preparation and properties of sodium salts of esters of nitrosulfoacetic acid. Russ Chem Bull 37, 2299–2306 (1988). https://doi.org/10.1007/BF00959883

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  • DOI: https://doi.org/10.1007/BF00959883

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