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Nitrosoalkylureas with a quaternary nitrogen atom. 6. Study of reaction kinetics of the decomposition in aqueous medium of nitrosoalkylureas based on monoquaternary alkylammonium salts

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The dependence of the rate of decomposition in aqueous solutions of dialkyl substituted nitrosoureas based on monoquaternary alkylammonium salts on pH conforms to the ElcB mechanism of decomposition.

  2. 2.

    A new compound of the chloroethylnitrosourea class has been discovered. Its rate of decomposition in neutral and weakly alkaline media is independent of pH.

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Literature cited

  1. A. A. Belyaev, V. F. Gopko, and L. B. Radina, Izv. Akad. Nauk SSSR, Ser. Khim., 553 (1985).

  2. A. A. Belyaev and L. B. Radina, Izv. Akad. Nauk SSSR, Ser. Khim., 2542 (1988).

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  5. Yu. Yu. Lur'e, Handbook on Analytical Chemistry [in Russian], Khimiya, Moscow (1971), p. 235.

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Authors and Affiliations

  1. Institute of Chemistry, Ural' Branch, Academy of Sciences of the USSR, Sverdlovsk

    A. A. Belyaev & L. B. Radina

Authors
  1. A. A. Belyaev
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  2. L. B. Radina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2545–2549, November, 1988.

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Belyaev, A.A., Radina, L.B. Nitrosoalkylureas with a quaternary nitrogen atom. 6. Study of reaction kinetics of the decomposition in aqueous medium of nitrosoalkylureas based on monoquaternary alkylammonium salts. Russ Chem Bull 37, 2296–2299 (1988). https://doi.org/10.1007/BF00959882

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  • DOI: https://doi.org/10.1007/BF00959882

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