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EPR study of the rearrangement of (C2H5)3SiCH2CH2ĊCl2 radicals

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

It has been established that the rearrangement of (C2H5)3Si(CH2)2ĊCl2 radicals into (C2H5)2Si(CH3CH)(CH2)2CCl2H takes place by an intramolecular mechanism with 1,5-migration of a hydrogen atom. The rate constant for the isomerization has been determined at 20°C and found to be (2.2 ± 0.3)·103 sec−1.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute for Organometallic Compounds, Academy of Sciences of the USSR, Moscow

    R. G. Gasanov & N. V. Blinova

Authors
  1. R. G. Gasanov
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  2. N. V. Blinova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2512–2516, November, 1988.

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Gasanov, R.G., Blinova, N.V. EPR study of the rearrangement of (C2H5)3SiCH2CH2ĊCl2 radicals. Russ Chem Bull 37, 2262–2266 (1988). https://doi.org/10.1007/BF00959874

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  • DOI: https://doi.org/10.1007/BF00959874

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