Skip to main content
SpringerLink
Log in

Complex formation of some pesticides with adenosine triphosphoric acid

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It was shown by the method of spectrofluorimetry that pesticides (bazagran, zenkor, kuzagard, lontrel, raundap, setoxidim, tachigaren, and tilt), as well as the metallocomplexes of the herbicide lontrel, form complexes with nucleotides (adenosine triphosphoric acid — ATP) and its chemical analog (ɛ-ATP), which are of the 1∶1 composition. The values of the constants of complex formation were determined.

  2. 2.

    The stability of the complexes of the nucleotides with the metallocomplexes of lontrel depends on the nature of the metal ion. The copper, cobalt, and nickel complexes of lontrel with the nucleotide are significantly more stable than the lontrel-nucleotide complex.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. N. N. Mel'nikov, K. V. Novozhilov, S. R. Belan, and T. N. Pylova, Handbook on Pesticides [in Russian], Khimiya, Moscow (1985), pp. 21, 28, 37, 51, 71, 93, 247, 274.

    Google Scholar 

  2. Z. G. Aliev, L. O. Atovmyan, E. A. Saratovskikh, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 11, 2495 (1988).

    Google Scholar 

  3. T. A. Kondrat'eva, R. I. Gvozdev, and L. V. Tat'yanenko, Khim. Geterotsikl. Soedin., 987 (1983).

  4. Y. Lam and G. Kotowycz, Can. J. Chem.,55, 3620 (1977).

    Google Scholar 

  5. B. E. Smith, D. J. Lowe, and R. C. Bray, Biochem. J.,135, 331 (1973).

    Google Scholar 

  6. R. D. Spencer, G. Weber, G. J. Folman, et al., Eur. J. Biochem.,45, 425 (1974).

    Google Scholar 

  7. T. A. Glassman, C. Cooper, L. W. Harrison, and T. Swift, Biochemistry,10, No. 5, 843 (1971).

    Google Scholar 

  8. N. N. Mel'nikov, Yu. A. Baskakov, and K. S. Bokarev, The Chemistry of Herbicides and Plant Growth Stimulators [in Russian], Goskhimizdat, Moscow (1954).

    Google Scholar 

  9. E. A. Saratovskikh and V. G. Kartsev, Kinetics and Mechanisms of Physicochemical Processes [in Russian], Transactions of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka (1986), p. 38.

    Google Scholar 

  10. B. P. Nikol'skii, Handbook of the Chemist [in Russian], Vol. 3, Khimiya, Moscow, Leningrad (1964), p. 81.

    Google Scholar 

  11. F. Umland, A. Janssen, D. Thierig, and G. Wunsch, Theorie und Practische Anwendung von Komplexbildnern in der Analytik, Verlag Chemie, Weinheim (1971).

    Google Scholar 

  12. B. Pullman and A. Pullman, Quantum Biochemistry, Wiley, New York (1963).

    Google Scholar 

  13. J. A. Secrist, J. R. Barrio, and N. J. Leonard, Biochemistry,11, 3499 (1972).

    Google Scholar 

  14. K. Fedtke, Biochemistry and Physiology of the Action of Herbicides [in Russian], Agropromizdat, Moscow (1985), p. 50.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    E. A. Saratovskikh, T. A. Kondrat'eva, B. L. Psikha, R. I. Gvozdev & V. G. Kartsev

Authors
  1. E. A. Saratovskikh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. A. Kondrat'eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. L. Psikha
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. R. I. Gvozdev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. G. Kartsev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2501–2507, November, 1988.

The authors thank G. I. Lichtenstein and N. F. Gol'dshleger for helpful discussion of the work.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Saratovskikh, E.A., Kondrat'eva, T.A., Psikha, B.L. et al. Complex formation of some pesticides with adenosine triphosphoric acid. Russ Chem Bull 37, 2252–2258 (1988). https://doi.org/10.1007/BF00959872

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00959872

Keywords

Search

Navigation