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Study of the features of sorption of metal ions from sea water on clinoptilolite from different deposits

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Internal diffusion is the rate-limiting stage of the kinetics of sorption of metal ions from sea water on different clinoptilolites. The dependence of the effective internal diffusion coefficients on the degree of ion exchange was established.

  2. 2.

    The distribution coefficients and single distribution coefficients of the metal ions were determined, and the orders of the sorption selectivity were established.

  3. 3.

    All of the clinoptilolites studied can be used for primary concentration of rubidium from sea water; it is expedient to use zeolites from the Dzegvi and Detzami deposits for extraction of strontium.

  4. 4.

    The differences in the selectivity of clinoptilolites from different deposits for metal ions are apparently due to the ratio of macrocations in them and the concentration of nonexchangeable K+ and Mg2+ ions in them.

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Authors and Affiliations

  1. V. I. Vernadskii Institute of Geochemistry and Analytical Chemistry, Academy of Sciences of the USSR, Moscow

    R. Kh. Khamizov, T. Yu. Butenko, L. V. Bronov, V. V. Skovyra & V. A. Novikova

  2. Institute of Chemistry, Far-East Scientific Center, Academy of Sciences of the USSR, Vladivostok

    R. Kh. Khamizov, T. Yu. Butenko, L. V. Bronov, V. V. Skovyra & V. A. Novikova

  3. Southern Sakhalin State Pedagogical Institute, USSR

    R. Kh. Khamizov, T. Yu. Butenko, L. V. Bronov, V. V. Skovyra & V. A. Novikova

Authors
  1. R. Kh. Khamizov
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  2. T. Yu. Butenko
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  3. L. V. Bronov
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  4. V. V. Skovyra
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  5. V. A. Novikova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2461–2466, November, 1988.

We would like to thank V. A. Nikashina for discussing the data in the article and her comments and S. B. Ivanov and T. A. Kaidalova for conducting the x-ray phase analysis of the zeolites.

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Khamizov, R.K., Butenko, T.Y., Bronov, L.V. et al. Study of the features of sorption of metal ions from sea water on clinoptilolite from different deposits. Russ Chem Bull 37, 2215–2219 (1988). https://doi.org/10.1007/BF00959863

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  • DOI: https://doi.org/10.1007/BF00959863

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