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Kinetic models of heterogeneous catalytic reactions (review)

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

A complex approach for obtaining comprehensively substantiated kinetic models in heterogeneous catalysis is proposed. The kinetic models of catalytic conversions of different classes of organic compounds, estabished for the first time by this method, are described. Some theoretical premises and the consequences of this study are examined.

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Literature cited

  1. S. L. Kiperman, Catalytic Hydrogenation, Chap. 1, Elsevier, Amsterdam (1986), p. 1.

    Google Scholar 

  2. S. L. Kiperman, Usp. Khim.,47, No. 1, 1 (1978).

    Google Scholar 

  3. S. L. Kiperman, Principles of Chemical Kinetics in Heterogeneous Catalysis [in Russian], Khimiya, Moscow (1979).

    Google Scholar 

  4. S. L. Kiperman, Kinet. Katal.,23, No. 6, 1429 (1982).

    Google Scholar 

  5. S. L. Kiperman, Theoretical Problems in the Kinetics of Catalytic Reactions [in Russian], Chernogolovka (1984), p. 12.

  6. S. L. Kiperman, Kinetic Problems in Heterogeneous Oxidative Catalysis [in Russian], VINITI, Moscow (1979).

    Google Scholar 

  7. S. L. Kiperman, Mechanism of Catalysis [in Russian], Part 1, Nauka, Novosibirsk (1984), p. 159.

    Google Scholar 

  8. S. L. Kiperman, Introduction to the Kinetics of Heterogeneous Catalytic Reactions [in Russian], Nauka, Moscow (1964).

    Google Scholar 

  9. S. L. Kiperman, Kinetics of Heterogeneous Catalytic Reactions. Methodological Problems of Kinetics [in Russian], Chernogolovka (1983), p. 5.

  10. F. A. Melamed, T. P. Gegenava, and S. L. Kiperman, Kinet. Katal.,16, No. 2, 512 (1975).

    Google Scholar 

  11. S. G. Bashkirova and S. L. Kiperman, Kinet. Katal.,11, No. 3, 631 (1970).

    Google Scholar 

  12. N. I. Koltsov and S. L. Kiperman, J. Res. Inst. Catal. Hokkaido Univ.,26, No. 2, 85 (1978).

    Google Scholar 

  13. S. L. Kiperman, Kinet. Katal.,22, No. 1, 30 (1981).

    Google Scholar 

  14. S. L. Kiperman, Izv. Akad. Nauk SSSR, Ser. Khim., No. 1, 50 (1984).

    Google Scholar 

  15. S. L. Kiperman, Theoretical Problems of the Kinetics of Catalytic Reactions [in Russian], Chernogolovka (1984), p. 12.

  16. T. M. Matveeva, N. V. Nekrasov, and S. L. Kiperman, Heterogeneous Catalysis, Proceedings of the 5th International Symposium [in Russian], Part 1, Sofia (1983), p. 207.

  17. S. L. Kiperman and V. S. Gadzhi-Kasumov, Izv. Akad. Nauk SSSR, Ser. Khim., No. 6, 1110 (1965).

    Google Scholar 

  18. Z. T. Beisembaeva, B. S. Gudkov, M. S. Kharson, N. I. Popov, and S. L. Kiperman, Izv. Akad. Nauk SSSR, Ser. Khim., No. 4, 949 (1975).

    Google Scholar 

  19. Z. T. Beisembaeva, B. S. Gudikov, and S. L. Kiperman, Izv. Akad. Nauk SSSR, Ser. Khim., No. 3, 525 (1984).

    Google Scholar 

  20. N. D. Gavrilova, M. S. Kharson, N. I. Kol'tsov, and S. L. Kiperman, Kinet. Katal.,31, No. 1, 137 (1990).

    Google Scholar 

  21. N. D. Gavrilova, M. S. Kharson, K. M. Gitis, and S. L. Kiperman, Kinet. Katal.,31, No. 6, 1382, 1386 (1990).

    Google Scholar 

  22. S. L. Kiperman, B. S. Gudkov, and N. E. Zlotina, Problems of Kinetics and Catalysis [in Russian], Vol. 15, Nauka, Moscow (1973), p. 110.

    Google Scholar 

  23. L. M. Mamaladze, B. S. Gudkov, and S. L. Kiperman, Kinetics-2 All-Union Conference [in Russian], Vol. 2, Nauka, Novosibirsk (1975), p. 112.

    Google Scholar 

  24. N. V. Nekrasov, B. S. Gudkov, and S. L. Kiperman, Dokl. Akad. Nauk SSSR,208, No. 5, 1150 (1973).

    Google Scholar 

  25. A. A. Slinkin, M. V. Khotuleva, B. S. Gudkov, T. N. Kucherova, and S. L. Kiperman, Kinet. Katal.,25, No. 4, 1014 (1984).

    Google Scholar 

  26. S. L. Kiperman, D. Shopov, A. Andreev, N. Zlotina, and B. Gudkov, Izv. Otd. Khim. Nauk Bolg. Akad. Nauk,4, No. 2, 237 (1971).

    Google Scholar 

  27. B. S. Gudkov, N. A. Gaidai, Kh. Kh. Aliev, and S. L. Kiperman, Unsteady State Processes in Catalysis, Utrecht (1990), p. 337.

  28. A. N. Subbotin, N. V. Nekrasov, V. I. Yakerson, et al., Kinet. Katal.,29, No. 4, 840 (1988); No. 5, 1136, 1141.

    Google Scholar 

  29. A. N. Subbotin, Author's Abstract of Candidate Dissertation in Chemical Sciences, N. D. Zelinskii Institute of Organic Chemistry, Moscow (1989).

    Google Scholar 

  30. G. L. Dzhaparidze, É. Sh. Kenchadze, T. P. Gegenava, N. V. Nekrasov, M. M. Kostyukovskii, and S. L. Kiperman, Kinet. Katal.,26, No. 3, 673 (1985).

    Google Scholar 

  31. D. Z. Levin, M. A. Besprozvannyi, F. A. Melamed, and S. L. Kiperman, Kinet. Katal.,12, No. 6, 1455 (1971).

    Google Scholar 

  32. D. Z. Levin, E. P. Prokof'ev, B. S. Gudkov, M. A. Besprozvannyi, and S. L. Kiperman, Kinet. Katal.,15, No. 1, 98 (1974).

    Google Scholar 

  33. Lyu Kam Lok (Luu Cam Loc), N. A. Gaidai, and S. L. Kiperman, Proc. 9th International Congress on Catalysis, Vol. 3 (1988), p. 1261.

    Google Scholar 

  34. Lyu Kam Lok, N. A. Gaidai, S. L. Kiperman, and Kho Shi Tkhoang, 5th Ail-Union Conference on the Mechanism of Catalytic Reactions [in Russian], Moscow (1990), p. 191.

  35. Lyu Kam Lok, N. A. Gaidai, S. L. Kiperman, and S. B. Kogan, Kinet. Katal.,31, No. 2, 483 (1990).

    Google Scholar 

  36. N. V. Voikina, L. A. Makhlis, O. K. Bogdanova, and S. L. Kiperman, Kinet. Katal.,15, No. 3, 657 (1974).

    Google Scholar 

  37. N. V. Voikina, S. L. Kiperman, and O. K. Bogdanova, Kinet. Katal.,18, No. 4, 918 (1977).

    Google Scholar 

  38. M. É. Butovskii, N. A. Gaidai, N. T. Kol'tsov, G. R. Kotel'nikov, A. N. Shishkin, L. V. Strunnikova, and S. L. Kiperman, Neftekhimiya,17, No. 2, 203; No. 3, 371 (1977).

    Google Scholar 

  39. N. A. Gaidai, M. É. Butovskii, N. I. Kol'tsov, R. G. Kotel'nikov, and S. L. Kiperman, Promst. Sintet. Kauch., No. 2, 4 (1977).

    Google Scholar 

  40. T. P. Gegenava and S. L. Kiperman, Preprints, All-Union Conference on the Mechanism of Heterogeneous Catalytic Reactions [in Russian], Moscow (1974).

  41. O. N. Medevedeva, A. S. Badrian, and S. L. Kiperman, Izv. Akad. Nauk SSSR, Ser. Khim., No. 1, 19 (1977).

    Google Scholar 

  42. S. A. Krasavin, M. S. Kharson, M. M. Kostyukovskii, O. V. Bragin, and S. L. Kiperman, Izv. Akad. Nauk SSSR, Ser. Khim., No. 6, 1231 (1982).

    Google Scholar 

  43. S. A. Grin', N. A. Gaidai, T. Yu. Sergeeva, B. S. Gudkov, N. I. Kol'tsov, and S. L. Kiperman, Kinet. Katal.,26, No. 4, 907 (1985).

    Google Scholar 

  44. M. S. Kharson, E. M. Davydov, and S. L. Kiperman, React. Kinet. Catal. Lett.,5, No. 1, 128 (1976).

    Google Scholar 

  45. M. S. Kharson, E. M. Davydov, and S. L. Kiperman, All-Union Conference on the Mechanism of Catalytic Reactions [in Russian], Vol. 1, Moscow (1978), p. 194.

    Google Scholar 

  46. I. A. Vartanov, Author's Abstract of Candidate Dissertation in Chemical Sciences, N. D. Zelinskii Institute of Organic Chemistry, Moscow (1984).

    Google Scholar 

  47. I. A. Vartanov, T. R. Dzigvashvili, M. S. Kharson, K. M. Mekhtiev, A. V. Dolidze, and S. L. Kiperman, Kinet. Katal.,26, No. 3, 668 (1985).

    Google Scholar 

  48. Zh. G. Yuskovets, N. V. Nekrasov, M. M. Kostyukovskii, M. V. Shimanskaya, and S. L. Kiperman, Kinet. Katal.,24, No. 5, 1134 (1983).

    Google Scholar 

  49. Zh. G. Yuskovets, N. V. Nekrasov, M. M. Kostyukovskii, M. V. Shimanskaya, and S. L. Kiperman, Kinet. Katal.,25, No. 6, 1361 (1984).

    Google Scholar 

  50. A. Kh. Mamedov, M. S. Kharson, N. M. Guseinov, V. S. Aliev, and S. L. Kiperman, Azerb. Khim. Zh., No. 3, 28 (1978).

    Google Scholar 

  51. M. S. Kharson, A. Kh. Mamedov, and S. L. Kiperman, Kinet. Katal.,15, No. 1, 107; No. 2, 353 (1984).

    Google Scholar 

  52. M. I. Temkin and N. V. Kul'kova, Kinet. Katal.,16, No. 5, 1211 (1975).

    Google Scholar 

  53. G. V. Shakhnovich, I. P. Belomestnikh, N. V. Nekrasov, et al., Appl. Catal.,12, No. 1, 23 (1984).

    Google Scholar 

  54. A. S. Dryakhlov and S. L. Kiperman, Dokl. Akad. Nauk SSSR,258, No. 1, 131; No. 4, 931 (1981).

    Google Scholar 

  55. S. L. Kiperman, 7th Soviet-Japanese Seminar on Catalysis [in Russian], Nauka, Novosibirsk (1983), p. 203.

    Google Scholar 

  56. S. L. Kiperman, 9th Soviet-Japanese Seminar on Catalysis, Novosibirsk (1990), p. 202.

  57. S. L. Kiperman, 3rd European Workshop Meeting on New Developments in Selective Oxidation, Louvain-la-Neuve, Preprints, Vol. 1, p. 1.

  58. V. P. Stasevich, T. M. Shaprinskaya, G. P. Korneichuk, et al., Kinet. Katal.,23, No. 5, 1290 (1982).

    Google Scholar 

  59. A. L. Turchaninov, N. V. Nekrasov, N. A. Gaidai, et al., Kinet. Katal.,28, No. 2, 386 (1987).

    Google Scholar 

  60. Z. A. Ibraeva, N. V. Nekrasov, M. M. Kostyukovskii, Z. T. Beisembaeva, V. I. Yakerson, and S. L. Kiperman, Kinet. Katal.,30, No. 6, 1393 (1989).

    Google Scholar 

  61. Z. A. Ibraeva, N. V. Nekrasov, Z. T. Beisembaeva, and S. L. Kiperman, Teor. Éksp. Khim.,24, No. 2, 268 (1988).

    Google Scholar 

  62. M. G. Slin'ko, V. S. Beskov, and N. A. Dubyaga, Dokl. Akad. Nauk SSSR,204, No. 5, 1174 (1972).

    Google Scholar 

  63. Z. A. Ibraeva, N. V. Nekrasov, M. M. Kostyukovskii, Z. T. Beisembaeva, V. I. Yakerson, and S. L. Kiperman, Kinet. Katal.,30, No. 6, 1393 (1989).

    Google Scholar 

  64. S. L. Kiperman, K. Kumbilieva, and L. Petrov, Ind. Chem. Eng. Res.,28, No. 2, 376 (1989).

    Google Scholar 

  65. M. M. Kostyukovskii and S. L. Kiperman, Chemical Kinetics in Catalysis. Theoretical Problems of Kinetics [in Russian], Chernogolovka (1985), p. 40.

  66. M. M. Kostyukovskii, Author's Abstract of Candidate Dissertation in Chemical Sciences, N. D. Zelinskii Institute of Organic Chemistry, Moscow (1986).

    Google Scholar 

  67. M. M. Kostyukovskii, V. S. Beskov, N. I. Kol'tsov, and S. L. Kiperman, Theoretical Problems of the Kinetics of Catalytic Reactions [in Russian], Chernogolovka (1984), p. 79.

  68. D. I. Mendeleev, Collected Works [in Russian], Vol. 8, Izd. Akad. Nauk SSSR, Moscow (1948), p. 126.

    Google Scholar 

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Review of data from research awarded the Academy of Sciences of the USSR D. I. Mendeleev Prize in chemical sciences for 1990.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2699–2717, December, 1991.

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Kiperman, S.L. Kinetic models of heterogeneous catalytic reactions (review). Russ Chem Bull 40, 2350–2365 (1991). https://doi.org/10.1007/BF00959702

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  • DOI: https://doi.org/10.1007/BF00959702

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