Effect of base on the state of palladium in the synthesis of styrene in the heck reaction

  • A. F. Shmidt
  • L. V. Mametova
  • T. V. Dmitrieva
  • E. Yu. Shmidt
  • V. S. Tkach
Brief Communications

Abstract

An extremely important role is shown for the tertiary amine in the reduction of Pd(II) formed as result of the reductive transformations of the aryl halide in the Heck reaction. The dependence of the rate on the nature of the base is explained.

Keywords

Palladium Styrene Halide Tertiary Amine Aryl Halide 

Literature cited

  1. 1.
    I. I. Moiseev, π-Complexes in the Liquid-Phase Oxidation of Olefins [in Russian], Khimiya, Moscow (1970), p. 45.Google Scholar
  2. 2.
    R. F. Heck, J. Am. Chem. Soc.,12, 213 (1982).Google Scholar
  3. 3.
    West German Patent No. 1,904,235 (1974).Google Scholar

Copyright information

© Plenum Publishing Corporation 1991

Authors and Affiliations

  • A. F. Shmidt
    • 1
  • L. V. Mametova
    • 1
  • T. V. Dmitrieva
    • 1
  • E. Yu. Shmidt
    • 1
  • V. S. Tkach
    • 1
  1. 1.Irkutsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRUSSR

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