Reactions of phosphorus pentachloride with N,N'-dialkyl- and N-alkyl-N'-acetylureas

  • B. V. Timokhin
  • V. K. Dmitriev
  • M. Yu. Dmitrichenko
  • G. V. Dolgushin
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Abstract

N,N′-dialkylureas are phosphorylated by phosphorus pentachloride to give cyclic trichlorodiazaphosphetidinones. The formation of these derivatives in the reaction of N-methyl-N' -chloroacetylurea with PCl5 is accompanied by the chlorination of the N-acetyl fragment.

Keywords

Phosphorus PCl5 Phosphorus Pentachloride Acetylureas 

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Copyright information

© Plenum Publishing Corporation 1991

Authors and Affiliations

  • B. V. Timokhin
    • 1
    • 2
  • V. K. Dmitriev
    • 1
    • 2
  • M. Yu. Dmitrichenko
    • 1
    • 2
  • G. V. Dolgushin
    • 1
    • 2
  1. 1.Irkutsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRUSSR
  2. 2.Institute of Petroleum and Coal Chemistry SynthesisIrkutsk State UniversityUSSR

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