Skip to main content
Log in

Rate constants and mechanism of the reactions of N(4S) atoms with methane and ethane

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The channel for the reaction of nitrogen atoms and methane yielding hydrogen atoms does not exceed 10% at ∼20‡C. The rate constant for the reaction of nitrogen atoms and ethane at ∼20‡C is (4 ± 2)·10−16 cm3/sec.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Literature cited

  1. I. V. Michael and I. H. Lee, Chem. Phys. Lett.,51, No. 2, 303 (1977).

    Google Scholar 

  2. I. V. Michael, Chem. Phys. Lett.,76, No. 1, 129 (1980).

    Google Scholar 

  3. V. Ya. Basevich, Khim. Fiz.,5, No. 7, 925 (1986).

    Google Scholar 

  4. E. N. Aleksandrov, V. I. Vedeneev, S. N. Kozlov, and G. A. Pryakhin, Izv. Akad. Nauk SSSR, Ser. Khim., No. 3, 746 (1988).

    Google Scholar 

  5. E. N. Aleksandrov, V. I. Vedeneev, S. N. Kozlov, and G. A. Pryakhin, Izv. Akad. Nauk SSSR, Ser. Khim., No. 10, 2407 (1988).

    Google Scholar 

  6. E. N. Aleksandrov, V. I. Vedeneev, S. N. Kozlov, et al., Khim. Fiz.,8, No. 8, 1089 (1989).

    Google Scholar 

  7. H. Blades and C. A. Winkler, Can. J. Chem.,29, No. 11, 1022 (1951).

    Google Scholar 

  8. P. A. Cartaganis and C. A. Winkler, Can. J. Chem.,34, No. 10, 1457 (1956).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 705–706, March, 1990.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Aleksandrov, E.N., Vedeneev, V.I., Kozlov, S.N. et al. Rate constants and mechanism of the reactions of N(4S) atoms with methane and ethane. Russ Chem Bull 39, 625–626 (1990). https://doi.org/10.1007/BF00959601

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00959601

Keywords

Navigation