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Free radicals formed upon the reaction of substituted benzoquinones with potassium and zinc butylxanthates

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Potassium and zinc butylxanthates undergo one-electron transfer upon reaction with benzoquinones to give semiquinone radicals. The thiyl radical arising as a result of electron abstraction from the butylxanthate anion may add to the aromatic ring of the semiquinone radical.

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Literature cited

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Authors and Affiliations

  1. V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe

    R. R. Rakhimov, P. M. Solozhenkin, V. S. Pupkov & A. I. Prokof'ev

  2. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    R. R. Rakhimov, P. M. Solozhenkin, V. S. Pupkov & A. I. Prokof'ev

Authors
  1. R. R. Rakhimov
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  2. P. M. Solozhenkin
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  3. V. S. Pupkov
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  4. A. I. Prokof'ev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 699–701, March, 1990.

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Rakhimov, R.R., Solozhenkin, P.M., Pupkov, V.S. et al. Free radicals formed upon the reaction of substituted benzoquinones with potassium and zinc butylxanthates. Russ Chem Bull 39, 619–621 (1990). https://doi.org/10.1007/BF00959599

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  • DOI: https://doi.org/10.1007/BF00959599

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