Abstract
2-Trifluoromethylperfluoro-2-pentenyl fluorosulfate undergoes SN2′ nucleophilic reactions. The reaction of this fluorosulfate with halide salts gives an equilibrium mixture of 1-halo-2-trifluoromethylperfluoro-2-pentene and 2-trifluoromethyl-3-haloperfluoro-1-pentene.
Literature cited
V. F. Cherstkov, S. R. Sterlin, L. S. German, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., No. 1, 220 (1985).
V. F. Cherstkov, M. V. Galakhov, S. R. Sterlin, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 8, 1864 (1985).
V. F. Cherstkov, S. R. Sterlin, L. S. German, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., No. 8, 1872 (1983).
V. F. Snegirev and K. N. Makarov, Izv. Akad. Nauk SSSR, Ser. Khim., No. 1, 106 (1985).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 695–698, March, 1990.
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Avetisyan, é.A., Cherstkov, V.F., Snegirev, V.F. et al. Reaction of 2-trifluoromethylperfluoro-2-pentenyl fluorosulfate with nucleophilic reagents. Russ Chem Bull 39, 615–618 (1990). https://doi.org/10.1007/BF00959597
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DOI: https://doi.org/10.1007/BF00959597