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Reactions of copper(II) polyfluorinated Β-diketonates and Β-ketoesterates with hydrazines

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

It has been shown that pyrazoles (hydroxypyrazoles) are formed upon reaction of fluorine-containing copper Β-diketonates (Β-ketoesterates) with hydrazines and their hydrochlorides. A preparative method has been developed for the synthesis of fluorinated pyrazoles and hydroxypyrazoles via treatment of fluorine-containing Β-diketonate and Β-ketoesterate copper compounds with hydrazines. The molecular structure of 1-phenyl-3-octafluorobutyl-5-hydroxypyrazole has been established based on x-ray structural analysis.

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Authors and Affiliations

  1. Institute of Chemistry Ural Branch, Academy of Sciences of the USSR, Sverdlovsk

    P. N. Kondrat'ev, Z. é. Skryabina, V. I. Saloutin, K. I. Pashkevich, N. A. Klyuev & G. G. Aleksandrov

Authors
  1. P. N. Kondrat'ev
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  2. Z. é. Skryabina
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  3. V. I. Saloutin
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  4. K. I. Pashkevich
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  5. N. A. Klyuev
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  6. G. G. Aleksandrov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 640–645, March, 1990.

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Kondrat'ev, P.N., Skryabina, Z.é., Saloutin, V.I. et al. Reactions of copper(II) polyfluorinated Β-diketonates and Β-ketoesterates with hydrazines. Russ Chem Bull 39, 561–565 (1990). https://doi.org/10.1007/BF00959584

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  • DOI: https://doi.org/10.1007/BF00959584

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