Abstract
It is shown for the first time that bromination and iodination of tertiary perfluorocarbanions are reversible. The tendency of teriary perfluoroalkyl halides to undergo dehalofluorination under the influence of weak bases depends on the structure of the perfluoroalkyl halide, and increases in going from lower to higher halides and from linear to cyclic compounds.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 636–640, March, 1990.
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Pletnev, S.I., Igumnov, S.M., Zakharova, E.V. et al. Synthesis and some properties of tertiary perfluoroalkyl halides. Russ Chem Bull 39, 557–560 (1990). https://doi.org/10.1007/BF00959583
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DOI: https://doi.org/10.1007/BF00959583