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Potential function of internal rotation of (CH3)2CClNO, CH3CCl2NO, and their deuterium analogs

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The potential function has been constructed for internal rotation of the NO-group in (CH3)2CClNO, CH3CCl2NO, and their deuterium analogs. It has been established that the N=O bond in the cisCl conformer of CH3CCl2NO does not eclipse the C-Cl bond, rather forming an angle of approximately 30‡. It has been shown that a change in substitutent on the α-carbon atom may produce a substantial change in the form of the potential function of internal rotation (PFIR) of the NO group.

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Authors and Affiliations

  1. Institute of Physiologically Active Substances, Academy of Sciences of the USSR, Chernogolovka

    S. V. Trepalin, A. V. Yarkov, V. B. Sokolov & A. N. Ivanov

Authors
  1. S. V. Trepalin
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  2. A. V. Yarkov
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  3. V. B. Sokolov
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  4. A. N. Ivanov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 550–555, March, 1990.

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Trepalin, S.V., Yarkov, A.V., Sokolov, V.B. et al. Potential function of internal rotation of (CH3)2CClNO, CH3CCl2NO, and their deuterium analogs. Russ Chem Bull 39, 476–480 (1990). https://doi.org/10.1007/BF00959564

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  • DOI: https://doi.org/10.1007/BF00959564

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